Shooting. Post is neat since you see the image come out as you envision it, but opening them up, seeing that you nailed the exposure, focus, composition the first time and you can just improve it from there is a great feeling. Even before that the thought that goes into your images (if you're setting them up carefully); playing with lighting, playing with angles, playing with distance, finally finding that right combo. Or if it's more fast paced, trying to keep up with the action and get good focus, adjusting exposure on the fly, being forced to compose and snap at just the right moment. It's all great stuff.