On a 1DII, the sensor size is 28.7mm across. That means that with a 1:1 lens, a subject that is that width across should exactly fill the frame from edge to edge. I would estimate that most wedding bands don't exceed 20cm across, so if you are shooting at maximum magnification with the EF 50mm f/2.5, 1:2, your frame will cover about 57.4 across; the complete ring would therefore occupy about 1/3 of the entire frame. Using a 1:1 lens like the Sigma, you will find that one ring will likely occupy about 2/3 of the entire frame.
Note that you may decide to shoot at a lower magnification to photograph more than 1 ring, add other props, improve the composition, etc.; I rarely find myself shooting at maximum magnification unless I'm trying to overrule the compositional quality of the photo with some real in-your-face blowup of a small object.