IIRC the grip on my original 5D drained one then the other.... Seems like the one on the 7D draws from both (I charged them last night, both were about half).....
You can usually check the meter in the menus (on later and higher model cameras) which will tell you how much power is left in each battery
If you have 2 sets of batteries, you must plan on shooting a LOT (and I mean a LOT). In all the airshows I've shot, I've never used a second set of batteries, usually shooting over 75GB of RAW too... On the 1D III and later cameras, I've never drained the first battery, those last forever.
If you want, carry a single spare, the grip works with only one battery in it too. That saves some weight when you want the grip (which I can't think of a reason to take it off) and you don't need a lot of battery power.
Mark H
Too Much Camera Stuff......