It's not just sharpenign effects, but also slight overexposure towards the top of the tower, especially in the doem and spire.
Also, how much sharpness do you expect? The top of the spire is only 3 pixels wide. To define any details is really impossible in that case. If you look at the grass in the foreground just beyond the stairs you see exactly the same thing. Do not that at 100 % you are looking at a rather large magnification, and you should stay away from th epicture twice the diagonal for normal viewing.
It is also debatable how much DoF you get from digital. I reckon it is about 40% less than from film (on FF), and no DoF calculators take this into account (yet), although shooters all over now start realizing that this is the case. On APS-C it is only 50% of film on APS-C, but it is less noticeable there due to the automatic increase in DoF due to the smaller medium.
However, IMO, the main culprits are slight overexposure, sharpening artefacts, and the small size of the details.
HTH, kind regards, Wim