They cost about the same, 100 slightly less (and on sale right now).
100 has IS and macro at f2.8. 135 has f2.0, which is even more pronounced impact at the longer Focal Length.
This is for art shooting. So; portraits, things, etc. but mostly portraits (and maybe portions of a wedding or two). Emphasis on "isolation".
Just wanted to gather thoughts.
As my gear list indicates, I have 85 f1.8 (presently my favorite lens on crop or FF), 70-200 f2.8 IS arriving Monday. It's such a big honker I'd sort of like a real performer art lens with less weight and attention.
Just can't decide, so collecting advice.
EF 100 f2.8L Macro IS ($880)


