Hi
You have been pointed in the correct direction above already by Dennis. This section is for the 'G' series Powershots so most of us in here are unfamilier with your model camera and cannot give you useful advice as we dont know what it can/cant do.
Saying that though theres nothing wrong with the SX series of cameras so a good picture is well within your grasp with the equipment you have. As has been already said your ISO is fairly high and this can cause a 'grainy' effect in a photo.
As someone who doesn't shoot portraits the only thing that stands out to me is a very busy background. A plain backdrop would bring the subjects, sorry your sister and her partner, into life. For me, at the moment, my eye is drawn to an interesting wall behind them which is a photograph in itself. My only other point is the contrasting items of clothing they have on. This may not be helping the camera when its metering for light, to balance the exposure.
These are only minor critisisms though, as I said I normally photograph birds and animals in which an uncluttered backdrop is preferred.
All in all, you have taken a nice picture so keep at it as your definately going in the right direction. The conversion to black and white is a nice touch too, and is my personal favourite of them both. Keep at it and read these forums, people are extremely helpful, albeit sometimes in a slightly confusing manner for beginners 
Best of luck,
Ian