I'm nearly three years in to this little photography adventure, and only now do I feel like I am able to "see" the light with any sort of consistency (and not that I always get it right, either!).
Neil pretty much got it spot on with the daylight. One of the ways to think about lighting is that the better* light generally comes from light sources that are effectively large. The larger the light source, the more the light will be coming from many directions, instead of a small light source where the light is basically all heading in the same direction by the time it reaches the subject. The sun is HUGE, but because it's so far away, it is thought of as a small light source since the light is very directionalized. This is also why an overcast sky at mid day is better for photos than a clear sky. By turning the entire sky into a giant diffuser, you are making the light source effectively bigger.
That last point is also why some people get all screwed up with soft-boxes. They think that, just by adding a soft box to a studio light, the light is going to be better. Then they put the light as far away as possible in the studio, and wonder why the images don't look better. By placing the light so far away, they've made the light effectively smaller, and basically negated the soft box.
*This gets a star because good light is also about what you're going for. If you need light to provide contrast (say, taking pictures designed to showcase texture), then a smaller effective light source is better. "Good" light is as much about what look you're going for as if the light is big or small.