Dobsonians, and also telescopes on what's called an Alt-Az mount, (like the Celestron above), aren't ideal for long exposure photographs, no. This is because, as you said Martyn, the image will rotate. I've never used one, so don't know how long you can shoot for before rotation becomes a problem. However, the free image stacking software, Deep Sky Stacker (DSS), does cater somewhat for image rotation. Telescopes on Equatorial Mounts are more suitable.
I've got pretty much the 11" version of that Celestron though, and I love it. Excellent for lunar and planetary viewing, and also pretty damn good on smaller deep sky objects. Even at the relatively slow f/10 I can still clearly see dim DSOs at a nice dark site. Could easily see (parts of) the Veil Nebula the other night.