Her face has enough contrast... if it was lit. But it wasn't. At best, you only had the street lights illuminating on the outline between her hair and her face. With the Single point focus, I'm pretty sure the algorithm doesn't even attempt to factor in the micro-contrast from the eyes.
What we also don't know (and only you do, and you might not even remember) is whether when you took the shot, did you select that AF point but made sure you took it w/o recomposing? But in that scenario, I wouldn't think it would have mattered much because the street in the back (to the right side of *her* head, our left) provides more lighting for the AF to lock on. Had you been in Spot-AF, I think the camera would have had a better chance, but AF would have been slowed down to a hunt.
In this situation... I would have tried to locked on to her left arm, where it meets the guy's shirt. There is contrast there... just as much as the face/hair, but at least it's low and will not have anything in the background to distract it. Or even the girl to camera's left, with the white long sleeve shirt. But again... it could be that we see contrast simply because the flash fired and lit up the subjects... whether the focus assist lamp was able to provide sufficient coverage or not... that's yet to be determined.
The FA lamp doesn't shoot all that wide (side-to-side, up-n-down).